Preheat the oven to 425℉. Butter or spray six (6-ounce) ramekins with baking spray. Set aside.
Add the chocolate chips and butter to a medium microwave safe mixing bowl. Heat for 1 minute while stirring in 15 second intervals. If needed, microwave an additional 15 seconds, until the chocolate is melted. Cool slightly.
½ cup bittersweet chocolate chips, ½ cup unsalted butter
In a large mixing bowl, use a hand mixer to beat the eggs and egg yolks until fully combined. Mix in powdered sugar and vanilla extract until combined.
2 large eggs, 3 egg yolks, 1 teaspoon vanilla extract, 1 cup powdered sugar
Pour in the cooled butter and chocolate mixture until well blended. Then use a spatula to stir in flour, salt and espresso powder, by hand, until just combined.
⅓ cup all-purpose flour, Pinch salt, ½ teaspoon espresso powder
Divide batter equally between ramekins (about ½ cup if using 6 ounce ramekins) and place them, evenly spaced apart, on a baking sheet.
Bake for 12-14 minutes or until edges are firm but cakes are soft and not quite set in the center.
Remove the cakes from the oven and allow them to sit for 1 minute before carefully inverting onto a small plate. Serve and enjoy!
See post for storage options, tips, variations, and answers to frequently asked questions.